p40 053

53. The radial probability function for the ground state of hydrogen is P (r) =(4r2/a3)e-2r/a, where a is

"
the Bohr radius. (See Eq. 40-31.) We want to evaluate the integral P (r) dr. Eq. 15 in the integral
0
table of Appendix E is an integral of this form. We set n = 2 and replace a in the given formula with
2/a and x with r. Then

" "
4 4 2
P (r) dr = r2e-2r/a dr = =1 .
a3 a3 (2/a)3
0 0

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