9818247192
It has to be noted that membranę temperaturę and gases partial pressures change with celi current: with increasing current, partial pressure of hydrogen or oxygen decreases, whereas temperaturę increases.
3.2. Activation \oltage drop
As shown in [1], the activation overpotential, including anodę and cathode, can be calculated by:
=-[ę, +ę2.7- + 43.7-./«(Co,) + 44.7-.M(i>c)] (7)
where irc is the celi operating current (A), the 4's represent parametric coefficients for each celi model, whose values are defined based on theoretical equations with kinetic, thermodynamic and electrochemical foundations [1]. co2 is the concentration of oxygen in the catalytic interface of the cathode (mol/cm3), determined by:
(8)
5.08.106-* T
3.3. Ohmie voltage drop
The ohmic voltage drop results from the resistance to the electrons transfer through the collecting plates and carbon electrodes, and the resistance to the protons transfer through the solid membranę. In this model, a generał expression for resistance is defined to include all the important parameters of the membranę. The equivalent resistance of the membranę is calculated by:
(9)
A
where Pm is the specific resistivity of the membranę for the electron flow (fi.cm), A is the celi active area (cm2) and t is the thickness of the membranę (cm), which serves as the electrolyte of the celi.
The membranes of the type Nafion® considered in this work, is a registered trademark of Dupont and broadly used in PEMFC. Dupont uses the following product designations to denote the thickness of the membranes Nafion:
Nafion 117: 7 mil (^ = 178 pm)
Nafion 115: 5 mil (i = 127 pm)
Nafion 112: 2 mil (^ = 51 pm)
The following numeric expression for the resistivity of the membranes Nafion is used [1]:
5
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